Journal
JOURNAL OF CLEANER PRODUCTION
Volume 292, Issue -, Pages -Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.jclepro.2021.125994
Keywords
CFRP recycling; Pyrolysis; Thermal decomposition of matrix; Pyrolytic carbon; Arrhenius-type kinetic behaviour; Activation energy
Categories
Funding
- Australian Government through the Australian Research Council's Discovery Early Career Researcher Award (DECRA) fellowship scheme [DE200100406]
- School of Civil Engineering at the University of Sydney
- Australian Centre for Microscopy and Microanalysis (ACMM) at the University of Sydney
- Australian Research Council [DE200100406] Funding Source: Australian Research Council
Ask authors/readers for more resources
This research investigates the kinetic behavior of thermal decomposition of CFRP up to 800 degrees C and reveals that the pyrolysis process consists of two stages, with majority of the polymer matrix removed in the first stage. Lower heating rates lead to higher conversion fractions with lower activation energies. Pyrolysis of the composite remains efficient until 425 degrees C and an oxidation process up to 550 degrees C is required for high quality recycled carbon fibre products.
Pyrolysis is a thermo-chemical method to recover clean fibres from carbon fibre reinforced polymer (CFRP) composite waste under oxygen-free conditions. To ensure the recovery quality and economic efficiency of reclaimed fibres, thermal decomposition of CFRP needs to be guided by the kinetic analysis. This paper investigates the kinetic behaviour of CFRP thermal decomposition at temperatures of up to 800 degrees C. A thermo-gravimetric method is used to monitor the thermal decomposition of CFRP samples during the pyrolysis process. The activation energies (E) required for different conversion fractions (alpha) are evaluated based on five different kinetic models: four Arrhenius-type model-free methods (Friedman, OFW, KAS and Starink) and one curve fitting method (Coats-Redfern). Pyrolysis of CFRP composite wastes show that the process consists of two stages, where majority of the polymer matrix (55%) is removed in the first stage of reaction. During stage one and up to 425 degrees C, lower heating rates successfully lead to higher conversion fractions with lower activation energies. Moreover, by investigating physical characteristics of the recycled fibres using scanning electron microscopy (SEM) and conversion kinetics of the recycling process, it is shown that pyrolysis of the composite remains efficient until 425 degrees C and an oxidation process up to 550 degrees C is required to achieve high quality recycled carbon fibre (rCF) products. The outcomes of this research contribute to optimisation of process variables and development of highly efficient and cost effective CFRP recycling method using pyrolysis technique. (C) 2021 Elsevier Ltd. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available