Journal
JOURNAL OF ALLOYS AND COMPOUNDS
Volume 879, Issue -, Pages -Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2021.160423
Keywords
Non-calcined strategy; Nanowire; Microsphere; Co-BTC MOF; Flexible asymmetric supercapacitor
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Funding
- National Natural Science Foundation of China [21304018]
- Natural Science Foundation of Jiangsu Province of China [BK20130619, BK20130617]
- Fundamental Research Funds for the Central Universities, Southeast University Zhishan Young Scholar Program
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By using a non-calcined strategy to synthesize nanowire microsphere shaped Co-BTC (CBNWM), the electrochemical properties of MOF have been significantly improved, leading to higher specific capacity and better cycling stability.
The exploration of an inexpensive, low-energy consumption and environmentally friendly preparation process to synthesize high capacitance performance MOF-based electrode materials is an important pre-requisite for their commercialization. We propose a non-calcined strategy to synthesize nanowire microsphere shaped Co-BTC (CBNWM). Making MOF into one-dimensional nanowire structure can effectively increase its active sites and the ion transfer rate. After the MOF nanowires are entangle and reunite into microspheres, their mechanical property and chemical stability are improved. Therefore, compared with Co-BTC crystal (CBC), the electrochemical properties of CBNWM have been significantly improved. The specific capacity of CBNWM reaches 1020 F g-1 at 5 mV s-1 or 657 F g-1 at 0.5 A g-1 with the capacity remains 81.4% after 3000 cycles. Subsequently, a flexible asymmetric device of CBNWM//AC was fabricated, whose maximum energy density can achieve 34.4 W h kg-1 with the related power density of 375.3 W kg-1. (c) 2021 Elsevier B.V. All rights reserved.
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