An all metal nitride nanostructure configuration: Study and exploitation in efficient photo-detection

Plasmonic metal and semiconductor hetero-structures in the nanometer regime render outstanding ingredients for efficient photodetection due to their complementary optical properties. While extracting surface plasmon generated hot carriers from such metal-semiconductor Schottky barriers have been reported widely, extraction of carriers generated from the interband transitions in the plasmonic metal nitride has not seen the forefront research yet. Here, we have explored the new aspect of extracting the interband transition generated charge carriers of plasmonic titanium nitride (TiNx) in an all metal nitride based device geometry with tantalum nitride (TaNx) as the base semiconductor matrix. The photoactive component of the device, TiNx/TaNx, shows two strong absorption peaks, one in the UV region and other in the visible region. The later indicates the well-known plasmon excitation of TiNx nanostructures whereas the former is due to its interband transition. The excitonic effect of TaNx further enhances the light absorption and charge carrier generation in the UV region. The fabricated device thus exhibits a substantial photoresponsivity of 42 mA/W and detectivity of 5.6 x 10(10) Jones under the UV illumination of wavelength 310 nm. We have also tried to exploit the tunability of plasmon resonance band in plasmonic TiNx and successfully fabricated a device which shows considerable photoresponse in the NIR and UV region as well, thus harvesting both plasmon induced hot carriers and interband transition generated carriers of TiNx in one single device configuration. The overall performance, cost efficiency and large scale integration possibilities make this all nitride detector a promising candidate for real-world applications. (C) 2021 Elsevier B.V. All rights reserved.

Automated summary

Exploring the extraction of charge carriers generated from the interband transitions in plasmonic titanium nitride (TiNx) in an all metal nitride based device geometry can achieve efficient photodetection. The device shows strong absorption peaks in both UV and visible regions, with substantial photoresponsivity and detectivity under UV illumination. The tunability of plasmon resonance band in plasmonic TiNx allows for considerable photoresponse in NIR and UV regions, making it a promising candidate for real-world applications.