Preparation of Si-α-Fe2O3/CdS composites with enhanced visible-light photocatalytic activity for p-nitrophenol degradation

Si-hematite (alpha-Fe2O3) nanosheets with highly exposed (110) facets were obtained first, and Si-alpha-Fe2O3/CdS composites were developed using a well-designed hydrothermal method. The prepared Si-alpha-Fe2O3/CdS composites showed enhanced visible-light photocatalytic activity compared with Si-alpha-Fe2O3 and CdS. The construction of the Si-alpha-Fe2O3/CdS heterojunction can inhibit the recombination of the photogenerated electron-hole pairs on the catalyst surface effectively. The synergistic effects of the photo-Fenton and the heterojunction promoted the production of the active species in the Si-alpha-Fe2O3/CdS system and enhanced the photocatalytic degradation activity under visible-light irradiation. The SFC-1:1 composite exhibited the highest photocatalytic activity toward p-nitrophenol degradation. The photocatalytic degradation mechanism was also investigated. (C) 2020 Elsevier B.V. All rights reserved.

Automated summary

Si-alpha-Fe2O3/CdS composites with highly exposed (110) facets exhibited enhanced visible-light photocatalytic activity due to the construction of the heterojunction, which effectively inhibits the recombination of photogenerated electron-hole pairs.