4.7 Article

Paraffin/methyl stearate/multi-walled carbon nanotubes composite phase change materials with wide service temperature and high latent heat

Journal

INTERNATIONAL JOURNAL OF ENERGY RESEARCH
Volume 45, Issue 9, Pages 13636-13645

Publisher

WILEY
DOI: 10.1002/er.6693

Keywords

form stability; phase change materials; phase change slurry; thermal energy storage; wide phase change temperature range

Funding

  1. State Key Laboratory of Polymer Materials Engineering [sklpme2020-2-5]

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The composite materials of paraffin/methyl stearate/multi-walled carbon nanotubes have a wide range of phase change temperatures and high latent heat, making them suitable for thermal energy storage applications.
The paraffin/methyl stearate/multi-walled carbon nanotubes composite form-stable phase change materials (FSPCMs) with a wide phase change temperature (T-pc) range and high latent heat (Delta H) and the subsequent phase change slurry (PCS) based on FSPCMs have been prepared via a direct impregnation method and via a simple dispersion method, respectively. The chemical structures, crystalline properties, surface microstructures, phase change properties, thermal reliability and stability of FSPCMs and the thermal storage and release performance were investigated. The FSPCMs had reversible melting/freezing phase change properties with a wider T-pc range from 21.6 degrees C to 55.3 degrees C than that of pure methyl stearate (from 16.2 degrees C to 32.5 degrees C) and high Delta H of 127 J/g. The FSPCMs had good thermal reliability and stability. The PCS presented evident thermal storage and release performance compared to pure water. The FSPCMs and PCS enable huge potential applications in thermal fields depending on wide T-pc range.

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