Journal
INORGANIC CHEMISTRY
Volume 60, Issue 11, Pages 7622-7626Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.1c00809
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Funding
- Key Laboratory of Ministry of Education on Advanced Energy Materials Chemistry, Program of Technology Innovation, Shanxi, China [2020L0650]
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A nitronyl nitroxide biradical with a capping N-donor group was found to enhance the single-molecule-magnet behavior of the Dy-biradical cluster, generating a magnetic reversal barrier of 146 K, which is the largest in the nitronyl nitroxide 4f system for Dy compounds.
A nitronyl nitroxide biradical with a capping N-donor group was discovered to improve single-molecule-magnet behavior of the Dy-biradical cluster, generating a magnetic reversal barrier of 146 K. As far as we know, the effective energy barrier of the Dy compound is largest in the nitronyl nitroxide 4f system by far.
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