Journal
INORGANIC CHEMISTRY
Volume 60, Issue 9, Pages 6218-6227Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.0c03693
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Funding
- National Science Foundation [1800387]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1800387] Funding Source: National Science Foundation
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This study examines the role of [Cu3O3](2+) in the conversion of methane to methanol by copper-exchanged zeolites, revealing that the Cu3+/Cu2+ couple does not participate in methane activation at the density functional theory ground state. Instead, methane activation is primarily driven by a combination of the Cu2+/Cu+ and oxyl/O2- redox couples. Comparison of X-ray absorption near-edge structure spectra indicates that methane activation by [Cu3O3](2+) results in the formation of Cu+ sites.
There is an ongoing debate regarding the role of [Cu3O3](2+) in methane-to-methanol conversion by copper-exchanged zeolites. Here, we perform electronic structure analysis and localized orbital bonding analysis to probe the redox chemistry of its Cu and mu-oxo sites. Also, the X-ray absorption near-edge structure, XANES, of methane activation in [Cu3O3](2+) is compared to that of the more ubiquitous [Cu2O](2+). Methane C-H activation is associated with only the Cu2+/Cu+ redox couple in [Cu2O](2+). For [Cu3O3](2+), there is no basis for the Cu3+/Cu2+ couple's participation at the density functional theory ground state. In [Cu3O3](2+), there are many possible intrazeolite intermediates for methane activation. In the nine possibilities that we examined, methane activation is driven by a combination of the Cu2+/Cu+ and oxyl/O2- redox couples. Based on this, the Cu 1s-edge XANES spectra of [Cu2O](2+) and [Cu3O3](2+) should both have energy signatures of Cu2+. Cu+ reduction during methane activation. This is indeed what we obtained from the calculated XANES spectra. [Cu2O](2+) and [Cu3O3](2+) intermediates with one Cu+ site are shifted by 0.91.7 eV, while those with two Cu+ sites are shifted by 3.0-4.2 eV. These are near a range of 2.5-3.2 eV observed experimentally after contacting methane with activated copper-exchanged zeolites. Thus, activation of methane by [Cu3O3](2+) will lead to formation of Cu+ sites. Importantly, for future quantitative XANES studies, involvement of O- + e(-) -> O-2- in [Cu3O3](2+) implies a disconnect between the overall reactivity and the number of electrons used in the Cu2+/Cu+ redox couple.
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