Journal
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Volume 2021, Issue 20, Pages 1913-1920Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.202100237
Keywords
Adducts; Azides; Cyanates; Cyanides; Pseudohalogens; Rhodanides
Categories
Funding
- Deutsche Forschungsgemeinschaft (DFG) [SCHU 1170/12-1]
- Projekt DEAL
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The Lewis acids GaCl3 and B(C6F5)(3) were used to treat Me3Si-X (X=CN, N-3, OCN, and SCN) in toluene, resulting in the desired adducts Me3Si-X -> GaCl3 and Me3Si-X -> B(C6F5)(3). The synthesized adducts were isolated, characterized, and analyzed for their structures, thermodynamics of formation, and charge transfer effects.
Me3Si-X (X=CN, N-3, OCN, and SCN) was treated with the Lewis acids GaCl3 and B(C6F5)(3) in toluene yielding the desired adducts Me3Si-X -> GaCl3 and Me3Si-X -> B(C6F5)(3). All synthesized adducts were isolated and completely characterized including single crystal structure elucidations. The different structures, thermodynamics of formation and charge transfer effects are discussed on the basis of experimental and theoretical data.
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