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Catalytic oxidation of CO on noble metal-based catalysts

Journal

ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
Volume 28, Issue 20, Pages 24847-24871

Publisher

SPRINGER HEIDELBERG
DOI: 10.1007/s11356-021-13008-3

Keywords

CO; Catalytic oxidation; Noble metal; Reaction mechanism

Funding

  1. National Key Research and Development Program of China [2018YFC0213400]
  2. National Natural Science Foundation of China [51938014]

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This article reviews recent research on the application of noble metal catalysts in the catalytic oxidation of CO, summarizing the effects of catalyst support, dopant, and physicochemical properties on the catalytic activity for CO oxidation. It emphatically discusses the influence of water vapor and sulfur dioxide on the catalytic activity in CO oxidation and presents several reaction mechanisms of CO catalytic oxidation on noble metal catalysts. Finally, the challenges of removing CO by catalytic oxidation in practical industrial flue gas are proposed.
Carbon monoxide (CO) catalytic oxidation has gained increasing interest in recent years due to its application prospects. The noble metal catalysts commonly exhibit outstanding CO catalytic oxidation activity. Therefore, this article reviewed the recent research on the application of noble metal catalysts in the catalytic oxidation of CO. The effects of catalyst support, dopant, and physicochemical properties on the catalytic activity for CO oxidation are summarized. The influence of the presence of water vapor and sulfur dioxide in the reaction atmosphere on the catalytic activity in CO oxidation is emphatically discussed. Moreover, this paper discussed several reaction mechanisms of CO catalytic oxidation on noble metal catalysts. Finally, the challenges of removing CO by catalytic oxidation in practical industrial flue gas are proposed.

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