4.7 Article

Construction of visible-light driven Bi2MoO6-rGO-TiO2 photocatalyst for effective ofloxacin degradation

Journal

ENVIRONMENTAL RESEARCH
Volume 199, Issue -, Pages -

Publisher

ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.envres.2021.111261

Keywords

Visible light; Ofloxacin; Reduced graphene oxide; Photocatalytic degradation; Photocurrent density

Funding

  1. National Research Foundation of Korea (NRF) - Korean government (MSIT) [2019R1A5A8080290]

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The study synthesized a ternary Bi2MoO6-rGO-TiO2 composite with excellent photocatalytic performance and analyzed its surface characteristics and catalytic decomposition efficiency, showing higher efficiency compared to pure and binary photocatalysts. Through the analysis of operational parameters, it was found that the ternary catalyst exhibited good photoelectric performance and effective charge separation.
Photocatalytic removal is more appropriate for the destruction of organic contaminants. The ternary Bi2MoO6reduced graphene oxide (rGO)-TiO2 catalyst was synthesized using a simple hydrothermal method, and various surface analytical optical techniques were analyzed. The photocatalytic decomposition efficiency of the Bi2MoO6-rGO-TiO2 composite was 92.3% higher than those of pure and binary photocatalysts. The effects of operational parameters, such as catalyst ratio, catalyst variation, rGO ratio variation, and pH value variation were also analyzed. The as-prepared ternary photocatalyst exhibited low photoluminescence and high photocurrent density, which suppressed photon-induced electron and hole (h+) recombination and effective charge separation. The study demonstrated that rGO has excellent electron transfer performance and enhanced photocatalytic reaction stability. The perfect cycling stability of Bi2MoO6-rGO-TiO2 was retained even after five consecutive cycles on the photocatalytic degradation reaction performance. In this study, we propose a decomposition performance mechanism for ofloxacin degradation that underwent visible-light irradiation.

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