Journal
ELECTROCHIMICA ACTA
Volume 377, Issue -, Pages -Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2021.138086
Keywords
Crystalline/amorphous heterostructure; Nickel vanadate; Cobalt boride; Supercapacitors; Energy storage
Categories
Funding
- National Natural Science Foundation of China [51971104, 51762031]
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Synthesis of active sites-rich Ni3V2O8@Co-B nanocomposites has overcome the issues of capacity decay and low electronic conductivity in nickel-based electrodes, showing great potential for high-performance energy storage materials.
The weak electronic conductivity and severe capacity decay are the major impediments that restrict the battery-type nickel-based electrodes with high theoretical capacity. In this report, active sites-rich nickel vanadium oxide@cobalt boride (Ni3V2O8@Co-B) nanocomposites with a particular heterostructure of crystalline core-amorphous shell are synthesized through a convenient and controlled strategy. In this structure, crystalline Ni3V2O8 mainly provides the capacity and maintains the stability of the structure, while amorphous Co-B facilitates the diffusion of ions and optimizes electronic conductivity, synergistically leading to a specific capacity of 216.1 mAh g(-1) (1789 F g(-1)) at 500 mA g(-1), which is 1.5 times of Ni3V2O8 and 3.8 times of Co-B. Also, an asymmetric supercapacitors device is fabricated based on the Ni3V2O8 @Co-B and activated carbon. The device displays an ultrahigh energy density of 91.2 Wh kg-1 at 400 W kg(-1). These results imply that Ni3V2O8@Co-B nanocomposites show great promise for highperformance energy storage materials, and the unique structure of crystalline/amorphous heterophase exhibits tremendous potential for electrochemical applications. (c) 2021 Elsevier Ltd. All rights reserved.
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