Journal
ELECTROCHIMICA ACTA
Volume 377, Issue -, Pages -Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2021.138074
Keywords
Ion-selective electrode; Amperometry; Flow injection analysis; Conducting polymer
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Funding
- Russian Science Foundation [19-13-00131]
- Russian Science Foundation [19-13-00131] Funding Source: Russian Science Foundation
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This study proposes flow injection amperometry as a potential alternative to classical potentiometry for solid contact ion-selective electrodes, providing faster response time and higher signal-to-noise ratio while eliminating background drift and potential instability.
In this work we propose a flow injection amperometry at constant potential as a perspective alternative to classical potentiometry for solid contact ion-selective electrodes (SC-ISEs). The amperometric readout mode eliminates the problem of background drift and potential instability ? common limitations of potentiometry for SC-ISEs. The selectivity in flowinjection and constant flow amperometric modes is similar to the potentiometric one. Moreover, flow injection amperometry in comparison to potentiometry for ion-selective electrodes provides a shorter response time, within 15?30 s, by two orders of magnitude decreased detection limit and 5-6 fold increased signal-to-noise ratio. The proposed approach is an attractive readout mode that opens new horizons for the improvement of performance characteristics of solid contact ISEs. ? 2021 Elsevier Ltd. All rights reserved. In this work we propose a flow injection amperometry at constant potential as a perspective alternative to classical potentiometry for solid contact ion-selective electrodes (SC-ISEs). The amperometric readout mode eliminates the problem of background drift and potential instability ? common limitations of potentiometry for SC-ISEs. The selectivity in flowinjection and constant flow amperometric modes is similar to the potentiometric one. Moreover, flow injection amperometry in comparison to potentiometry for ion-selective electrodes provides a shorter response time, within 15?30 s, by two orders of magnitude decreased detection limit and 5-6 fold increased signal-to-noise ratio. The proposed approach is an attractive readout mode that opens new horizons for the improvement of performance characteristics of solid contact ISEs.
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