4.7 Article

Rare-Earth Metal-Organic Framework@Graphene Oxide Composites As High-Efficiency Microwave Absorbents

Journal

CRYSTAL GROWTH & DESIGN
Volume 21, Issue 5, Pages 2668-2679

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.cgd.0c01555

Keywords

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Funding

  1. National Key Research and Development Project [2019YFC0312101]
  2. National Natural Science Foundation of China-Shandong Joint Fund [U1706225]

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The study presents a simple strategy to prepare metal-organic framework@graphene oxide composite materials with excellent microwave absorption performance, demonstrating that the effective absorption of electromagnetic waves is achieved through various mechanisms such as conduction loss, dipole and interface polarization, and balanced impedance matching.
Metal-organic framework (MOF)@graphene oxide (GO) composite material is a material with the advantages of GO and MOF, which can be an effective electromagnetic wave absorber. This study proposes a simple strategy to prepare MOF@GO composite materials to effectively absorb electromagnetic waves by adjusting Er, Sm, and Yb as well as adding GO to form a 3D cuboid structure. The cuboid structure of trimetal MOF@GO shows excellent microwave absorption, with the filler content being as low as 16 wt %. The reflection loss (RLmin) is -49.1 dB, and the corresponding effective absorption bandwidth (RL < -10 dB) reaches 6.72 GHz. Effective electromagnetic wave absorption stems from conduction loss, dipole and interface polarization, multiple EMW scattering, electron spin, and balanced impedance matching.

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