4.7 Article

Cracking and exfoliation behavior of oxide scale on T91 steel under different tensile stresses in oxygen-controlled lead-bismuth eutectic at 550 °C

Journal

CORROSION SCIENCE
Volume 183, Issue -, Pages -

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.corsci.2021.109324

Keywords

Stress corrosion; Lead-bismuth eutectic; Oxide scale; Cracking; Exfoliation

Funding

  1. National Key R&D Program of China [2018YFE0122100]
  2. National Natural Science Foundation of China [51501185, 51401204, 51901224]

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The study investigated the effect of different tensile stresses on cracking and exfoliation behavior of oxide scale for T91 steel in a lead-bismuth eutectic environment. Results showed that the exfoliation area of magnetite increased with stress, with cracks originating at the outer sublayer of spinel and propagating inward. A model was proposed to explain these phenomena, providing insights into the material behavior under different stress conditions.
The effect of different tensile stresses (0-180 MPa) on cracking and exfoliation behavior of oxide scale for T91 steel was studied in lead-bismuth eutectic containing 10-6 wt% oxygen concentration at 550 ?C. The results demonstrate that the exfoliation area of magnetite increased with stress. When tensile stress reached about 180 MPa, only a little magnetite remained; the outer sub-layer of spinel began to crack and locally exfoliated, exposing the inner sub-layer of spinel. The cracks with four different morphologies originated at the outer sublayer of spinel and propagated inward. A model was proposed to explain these phenomena.

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