4.8 Review

Proton conductive N-heterocyclic metal-organic frameworks

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Summary: Two novel anionic single-walled metal-organic nanotubes, FJU-105 and FJU-106, were successfully achieved using [In-6(cdc)(6)](6+) metalloring cluster as the secondary building blocks. FJU-106, with functionalized inner surface by uncoordinated -COOH groups of the H-btc linkers, shows higher proton conduction than FJU-105. Proton conduction performances of up to 1.80 x 10-(2) S cm (-1) were observed in FJU-106 at 70 degrees C, making it the best performer among MONTs.

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