4.5 Article

Functionalized multi-walled carbon nanotubes for oil spill cleanup from water

Journal

CLEAN TECHNOLOGIES AND ENVIRONMENTAL POLICY
Volume 24, Issue 2, Pages 519-541

Publisher

SPRINGER
DOI: 10.1007/s10098-021-02104-0

Keywords

Adsorbent; Oil spill; Metal oxide; Nanoparticles; Organic pollutants; Carbon nanotubes

Funding

  1. University of Pannonia [GINOP-2.3.2-15-2016-00016]

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The growing global economy has led to an increase in transportation and oil exploitation, resulting in oil spillage as a serious threat to aquatic and terrestrial ecosystems. Water purification has become a major challenge worldwide. Traditional adsorbents for oil removal have drawbacks, leading research efforts to focus on finding adsorbents with improved oil adsorption capabilities, such as nano-adsorbents like multi-walled carbon nanotubes.
The growing global economy resulted in an incessant increase in transportation and exploitation of oil. Hence, the oil spillage has been considered a serious threat to aquatic and terrestrial ecosystems. Therefore, water purification has been considered a major challenge around the world. There are numerous classical methods available for oil removal from water, but owing to multiple defects and disadvantages, research efforts have focused to find such adsorbents which can improve oil adsorption capability. Traditional adsorbent material typically applied in oil removal includes activated carbon, organoclays, wool, zeolites, etc. These materials suffer from several drawbacks such as low absorption capacity, non-selective absorption, and complicated reusability, whereas nano-adsorbents offer multiple advantages such as having multiple sorption sites, large surface area, short intra-particle diffusion distance, tuneable pore size, and ease of low-temperature modification. Multi-walled carbon nanotubes (MWCNTs) are extensively used adsorbent materials with a strong affinity for the removal of organic pollutants. The functionalization MWCNTs further increase the sorption capacity of adsorbents manifolds to remove organic materials. These nanocomposites are also compatible with green materials and considered environmentally friendly adsorbents. This review paper aims at providing an insight to understand the properties of the MWCNTs and their potential use to adsorb hydrocarbons from water. Moreover, the synthesis methods of those materials, their modification procedures including the functionalization with metal oxide nanoparticles, and applications are also discussed in detail.

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