4.8 Article

Functional Ion Gels: Versatile Electrolyte Platforms for Electrochemical Applications

Journal

CHEMISTRY OF MATERIALS
Volume 33, Issue 8, Pages 2683-2705

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.chemmater.1c00330

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Funding

  1. National Research Foundation of Korea (NRF) - Korea government (MSIT) [NRF-2019R1C1C1002435]
  2. National Research Foundation of Korea (NRF) - Ministry of Science and ICT for Original Technology Program [NRF-2020M3D1A2102869]

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Ion gels, composed of room-temperature ionic liquids and polymer gelators, are attractive solid-state electrolytes for functional electrochemical applications due to their tunable properties and compatibility with various processes. Recent studies have focused on improving their functionality through copolymer gelators and incorporation of redox species, showcasing their versatile applications in electrochemical displays, sensory systems, and energy generation/storage systems.
Ion gels consisting of room-temperature ionic liquids and polymer gelators are considered attractive solid-state electrolyte platforms for functional electrochemical applications due to their tunable electrochemical/mechanical properties, nonvolatility even in a vacuum, and compatibility with various solution processes. Accordingly, a number of studies have been reported on improving the functionality of ion gels and their use in diverse applications. In this Perspective, we highlight recent representative advances in the development of functional gels based on judiciously designed copolymer gelators or prepared by incorporating redox species. In addition, we introduce versatile applicability of ion gels in a variety of applications including electrochemical displays, smart sensory systems, and energy generation/ storage systems.

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