4.8 Review

Quantum Plasmonic Sensors

Journal

CHEMICAL REVIEWS
Volume 121, Issue 8, Pages 4743-4804

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.chemrev.0c01028

Keywords

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Funding

  1. Volkswagen Foundation
  2. VIRTMAT project
  3. KIAS Individual Grant via the Quantum Universe Center [QP081101]
  4. U.S. Department of Energy, Office of Science, Basic Energy Sciences, Materials Sciences and Engineering Division
  5. Ministry of Science and ICT [2020R1A2C1010014]
  6. Institute of Information & Communications Technology Planning & Evaluation (IITP) - Korea government (MSIT) [2019-0-00296]
  7. South African National Research Foundation
  8. Council for Scientific and Industrial Research National Laser Centre
  9. South African Research Chair Initiative of the Department of Science and Innovation and National Research Foundation
  10. Basic Science Research Program through the National Research Foundation (NRF) of Korea
  11. National Research Foundation of Korea [QP081101, 2020R1A2C1010014] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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The article discusses the extraordinary sensitivity of plasmonic sensors in the field of biochemical sensing, as well as the application of quantum techniques to enhance sensor performance. It covers the general framework of quantum plasmonic sensing developed in recent years and highlights important works in this area.
The extraordinary sensitivity of plasmonic sensors is well-known in the optics and photonics community. These sensors exploit simultaneously the enhancement and the localization of electromagnetic fields close to the interface between a metal and a dielectric. This enables, for example, the design of integrated biochemical sensors at scales far below the diffraction limit. Despite their practical realization and successful commercialization, the sensitivity and associated precision of plasmonic sensors are starting to reach their fundamental classical limit given by quantum fluctuations of light-known as the shot-noise limit. To improve the sensing performance of these sensors beyond the classical limit, quantum resources are increasingly being employed. This area of research has become known as quantum plasmonic sensing, and it has experienced substantial activity in recent years for applications in chemical and biological sensing. This review aims to cover both plasmonic and quantum techniques for sensing, and it shows how they have been merged to enhance the performance of plasmonic sensors beyond traditional methods. We discuss the general framework developed for quantum plasmonic sensing in recent years, covering the basic theory behind the advancements made, and describe the important works that made these advancements. We also describe several key works in detail, highlighting their motivation, the working principles behind them, and their future impact. The intention of the review is to set a foundation for a burgeoning field of research that is currently being explored out of intellectual curiosity and for a wide range of practical applications in biochemistry, medicine, and pharmaceutical research.

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