4.7 Article

Comparison of the effects of Mg and Zn on the interface mismatch and compression properties of 50 vol% TiB2/Al composites

Journal

CERAMICS INTERNATIONAL
Volume 47, Issue 15, Pages 22121-22129

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2021.04.234

Keywords

Composites; Matrix alloying; Interface mismatch; Microstructures; Compression properties

Funding

  1. National Natural Science Foundation of China [51971101, 51701086]
  2. Postdoctoral Science Foundation of China [2020M670849]
  3. Guangdong Basic and Applied Basic Research Foundation, China [2019A1515110268]

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The study found that Mg has a better refining effect on TiB2 ceramic particles and can reduce the crystallographic mismatch degree of the Al/TiB2 interface. The addition of 6 wt% Mg significantly improves the strength and plasticity of the composite, while the addition of Zn leads to interface matching degree deterioration and sacrifices plasticity.
Low ductility limits the extensive application of high volume fraction (>30 vol%) ceramic particle-reinforced metal matrix composites, and the simultaneous improvement of strength and ductility is still a challenge owing to the smaller amount of matrix contained in such composites. In this paper, the effects of various contents of Mg or Zn (0, 6, 10 and 14 wt%) on the interface mismatch and compression properties of 50 vol% TiB2/Al composite fabricated in situ are comparatively studied. The results indicate that Mg has a better refinement effect than Zn on the TiB2 ceramic particles. Mg can reduce the crystallographic mismatch degree of the Al/TiB2 interface. 6 wt% Mg simultaneously increases the o0.2, oUCS and epsilon f of the composite into 780 MPa, 1162 MPa and 10.68%, compared with the composite without the addition of Mg, increasing 8.5%, 2.8% and 30.6%, respectively. However, the addition of Zn leads to serious distortion of the Al lattice and deteriorates the interface matching degree of Al/TiB2, so the addition of Zn generally improves the o0.2 and oUCS while sacrifices the plasticity simultaneously. Furthermore, the contributions of various strengthening mechanisms of the matrix in the high volume fraction TiB2/Al composites are analyzed through a comparative study.

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