4.7 Article

Cobalt substitution effects on critical current, inter-grain full penetration field, and critical temperature study for Tl2Ba2Ca2Cu3-xCoxOy bulk superconductor, where x is from 0.005 to 0.050

Journal

CERAMICS INTERNATIONAL
Volume 47, Issue 13, Pages 18998-19006

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2021.03.244

Keywords

Thallium-based superconductors; Cuprates; Critical current; Critical temperature; High-temperature superconductivity

Funding

  1. Polish National Science Centre [DEC-2018/02/X/ST3/01741]

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This study demonstrates that thallium-based cuprates can exhibit high critical temperatures by partially substituting copper with transition elements.
Thallium-based cuprates are known to exhibit high critical temperatures and currents. Usually, partial substitution of copper by transition elements leads to the suppression of superconducting properties. This contribution reports on the studies of Tl2Ba2Ca2Cu3-xCoxOy. All specimens were found to be superconductors with critical temperatures of 102.4 K, 112.9 K, 112.2 K, 113.5 K, 112.8 K, and 94.8 K for x = 0.005, 0.010, 0.020, 0.030, 0.040, and 0.050, respectively. The samples were characterised by scanning electron microscopy, X-ray diffraction, AC susceptibility, resistance, and vibrating sample magnetometry.

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