4.7 Article

Effects of rare earth elements doping on gas sensing properties of ZnO nanowires

Journal

CERAMICS INTERNATIONAL
Volume 47, Issue 17, Pages 24218-24226

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2021.05.133

Keywords

Rare earth elements; ZnO; Nanowires; Ethanol; Gas sensing

Funding

  1. National Natural Science Foundation of China [51422402]
  2. Fundamental Research Funds for the Central Universities [N180102032, N180106002]
  3. Liaoning Revitalization Talents Program [XLYC1807160]

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The effects of rare earth elements doping on ZnO nanowires' gas sensing properties were investigated and 1% Ce-doped ZnO nanowires sensor exhibited the highest ethanol response. The study indicates that gas sensing performance of ZnO nanowires can be modified by doping different elements.
The effects of rare earth elements (Ce, Eu, and Er) doping on the microstructure and gas sensing properties of ZnO nanowires were investigated. The Ce, Eu, Er-doped ZnO nanowires and pristine ZnO nanowires were synthesized via a solvothermal route. The structure of the prepared samples was studied and compared by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, and X-ray photoelectron microscopy. The gas sensors were fabricated by coating the prepared samples on aluminum oxides tube-based Au sensing electrode, with Ni-Cr heating wire to control the operating temperature. The operating temperature of all sensors was determined to be 300 degrees C with consideration of ethanol response. At this temperature, all sensors showed good ethanol sensing performance, with the 1%Ce-doped ZnO nanowires-based sensor exhibited the highest ethanol response over the other sensors. The mechanism for the microstructure and gas sensing behavior difference of various samples was discussed.

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