Journal
CERAMICS INTERNATIONAL
Volume 47, Issue 15, Pages 21367-21372Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2021.04.145
Keywords
As3Mo8V4; PANi; rGO composite; Electrode; Supercapacitor
Categories
Funding
- Project of Talent Recruitment of Guangdong University of Petrochemical Technology [2019rc052, 2019rc054]
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The As3Mo8V4/PANi/rGO composite demonstrates exceptional specific capacitance (2351 F g-1 at 1 A g-1) and remarkable cyclic stability (96.9% after 5000 cycles). The symmetric supercapacitor exhibits high specific capacitance of 1295 F g-1 at 1 A g-1 and excellent energy density of 88.1 Wh kg-1 at power density of 349.6 W kg-1, with notable capacitance retention of 85.7% after 5000 cycles at 2 A g-1, indicating its potential for energy storage device applications.
Herein, [As2 IIIAsVMo8 VIV4 IVO40]2[CuICu2 II(pz)4]2.9H2O/polyaniline/reduced graphene oxide (pz = pyrazine, abbreviated to As3Mo8V4/PANi/rGO) composite is first assembled, characterized and systematically explored for its supercapacitor performance. As3Mo8V4/PANi/rGO composite shows a exceptional specific capacitance (2351 F g- 1 at 1 A g-1) and outstanding cyclic stability (96.9% after 5000 cycles). The symmetric supercapacitor exhibits high specific capacitance of 1295 F g-1 at 1 A g-1 and excellent energy density of 88.1 Wh kg-1 at power density of 349.6 W kg-1, while maintaining a notable capacitance retention of 85.7% after 5000 cycles at 2 A g-1. The above results confirm the potential application of As3Mo8V4/PANi/rGO composite in energy storage devices.
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