4.7 Article

Material proposal for 2D indium oxide

Journal

APPLIED SURFACE SCIENCE
Volume 548, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.apsusc.2021.149275

Keywords

2D oxides; Metal organic chemical vapor deposition; Conductive atomic force microscopy; Scanning transmission electron microscopy

Funding

  1. FLAG-ERA 2015 JTC project GRIFONE through Swedish Research Council [VR 2015-06816]
  2. National Research Development and Innovation Office, Hungary [NN 118914]
  3. Italian Ministry of Education and Research (MIUR) under the project EleGaNTe [PON ARS01_01007]
  4. European Structural and Investment Funds [VEKOP-2.3.3-15-2016-00002]
  5. Swedish Foundation for Strategic Research (SSF) [RIF 14-0074]
  6. Knut and Alice Wallenberg's Foundation
  7. [VR 2017-04071]
  8. Swedish Research Council [2015-06816] Funding Source: Swedish Research Council

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This study successfully demonstrated the formation of a novel 2D indium oxide, achieved through targeted intercalation and deposition of indium atoms at the graphene/SiC interface. A unique structural configuration with two sub-layers of indium atoms was observed, and bonding of oxygen atoms to indium atoms was confirmed. The 2D indium oxide exhibited a wide bandgap energy of 4.1 eV as estimated by conductive atomic force microscopy measurements.
Realization of semiconductor materials at the two-dimensional (2D) limit can elicit exceptional and diversified performance exercising transformative influence on modern technology. We report experimental evidence for the formation of conceptually new 2D indium oxide (InO) and its material characteristics. The formation of 2D InO was harvested through targeted intercalation of indium (In) atoms and deposition kinetics at graphene/SiC interface using a robust metal organic chemical vapor deposition (MOCVD) process. A distinct structural configuration of two sub-layers of In atoms in atop positions was imaged by scanning transmission electron microscopy (STEM). The bonding of oxygen atoms to indium atoms was indicated using electron energy loss spectroscopy (EELS). A wide bandgap energy measuring a value of 4.1 eV was estimated by conductive atomic force microscopy measurements (C-AFM) for the 2D InO.

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