Super-hydrophilic microporous biochar from biowaste for supercapacitor application

Super-hydrophilic microporous biochar materials, for supercapacitor application, are prepared through a simple and safe method from pomelo peel. Zinc nitrate and urea are used as activator, porogen and nitrogen source, which generate gases moderately and avoid the risk of explosion in calcination. This method endows the biochar products with abundant micropores and extraordinary large N and O doping content (>20% in atomic ratio). Such large doping content leads to super-hydrophilicity, which in turn makes the micropores available for charge storage. In addition, under a moderate calcination condition (700 celcius, 2 h), the biochar material gains large conductivity, without diminishing the super-hydrophilicity. Theoretical analysis on characterizations demonstrates that, the higher ratio of sp2 C and larger proportion of quaternary N (N-Q) in this material (CNO700) account for its much higher conductivity. The synergetic effect of large pore volume (0.69 cm3 center dot g- 1), high N and O doping content, proper ratio of N species and large conductivity (0.713 S center dot m- 1) makes the material (CNO700) exhibit high and durable specific capacitance, i.e., 391.0 F center dot g- 1 at 0.5 A center dot g- 1, and cycling stably for >25,000 times at 10.0 A center dot g- 1 with good capacitance retention.

Automated summary

Super-hydrophilic microporous biochar materials are prepared from pomelo peel using zinc nitrate and urea as activators, porogens, and nitrogen sources. The materials have abundant micropores and high N and O doping content, leading to super-hydrophilicity and excellent charge storage capabilities. The material exhibits high and durable specific capacitance, with good capacitance retention even after cycling over 25,000 times at high current densities.