Journal
APPLIED CATALYSIS B-ENVIRONMENTAL
Volume 284, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.apcatb.2020.119738
Keywords
Metal-organic frameworks; Mott-Schottky contact; Electrocatalysts; Molybdenum carbide; Water electrolysis
Funding
- National Natural Science Foundation of China [51802252, 51771144]
- Natural Science Foundation of Shaanxi Province [2020JM-032, 2019TD020, 2017JZ015]
- Natural Science Foundation of Jiangsu Province [BK20180237]
- 111 project 2.0 [BP2018008]
- Fundamental Research Funds for the Central Universities
- State Key Laboratory for Powder Metallurgy, Central South University, Changsha
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In this study, a porous nitrogen-doped carbon wrapped Co-Mo2C dual Mott-Schottky heterostructure was successfully fabricated for water electrolysis. The heterostructure showed fast kinetics and low overpotentials for hydrogen/oxygen evolution reactions, indicating its potential as an efficient electrocatalyst for water splitting. Density function theory calculations demonstrated that the interface correlation is favorable to water transfer by electron and speeds up adsorption and water dissociation, highlighting the promising prospects for MOF derived Mott-Schottky electrocatalysts in highly efficient water electrolysis.
Efficient, inexpensive and stable electrocatalysts are challenging and desperately required in order to complement the water electrolysis of noble metal catalysts. Herein, a porous nitrogen-doped carbon wrapped Co-Mo2C dual Mott-Schottky heterostructure has been successfully fabricated by carbonization of Co-Zn bimetal metal-organic framework (MOF) for water electrolysis. The heterostructure is found to feature with Co and Mo2C nanoparticles uniformly encapsulated in the highly porous leaf-like N-doped carbon nanosheet matrix. Such a thin porous dual-Mott-Schottky configuration can afford abundant surface active sites and the boosted electron transfer to promote the water splitting. As for hydrogen/oxygen evolution reaction (HER/OER), it has demonstrated fast kinetics and low overpotentials of 92 mV (HER) and 338 mV (OER) at a current density of 10 mA cm(-2) in 1 M KOH. Furthermore, the overall water splitting is stably delivered with a low cell voltage of 1.68 V at 10 mA cm(-2) in 1 M KOH. Density function theory (DFT) calculations demonstrate that the interface correlation is favorable to water transfer by electron and speeds up adsorption and water dissociation. The work here opens up interesting possibilities for the rational design and innovation of MOF derived Mott-Schottky electrocatalysts for highly efficient water electrolysis.
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