Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 60, Issue 21, Pages 11804-11808Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.202102509
Keywords
carbon quaternary stereocenters; copper-catalyzed carbomagnesiation; diastereoselectivity; persubstituted cyclopropanes
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Funding
- Israel Science Foundation [330/17]
- Ministry of Science and Technology [2023994]
- Sir Michael and Lady Sobell Academic Chair
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The regio- and diastereoselective copper-catalyzed carbomagnesiation reaction of cyclopropenes provides an easy and efficient access to novel persubstituted cyclopropyl cores with complete regio- and diastereoselectivity, despite the highly strained nature of cyclopropanes possessing three vicinal quaternary carbon stereocenters.
Despite the highly strained nature of cyclopropanes possessing three vicinal quaternary carbon stereocenters, the regio- and diastereoselective copper-catalyzed carbomagnesiation reaction of cyclopropenes provides an easy and efficient access to these novel persubstituted cyclopropyl cores with a complete regio- and diastereoselectivity.
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