4.8 Article

Molybdenum-Catalyzed Deoxygenative Cyclopropanation of 1,2-Dicarbonyl or Monocarbonyl Compounds

Related references

Note: Only part of the references are listed.
Review Chemistry, Multidisciplinary

Nitrene Transfer and Carbene Transfer in Gold Catalysis

Long-Wu Ye et al.

Summary: Gold-catalyzed transformations involving nitrene-transfer reactions and carbene-transfer reactions represent significant advances in homogeneous transition metal catalysis, with diverse product outcomes and high selectivity. The mechanisms behind these processes are complex, but the use of gold catalysts provides unique opportunities for selective and diverse chemical transformations.

CHEMICAL REVIEWS (2021)

Review Chemistry, Multidisciplinary

1,2-Migrations onto Gold Carbene Centers

Tao Wang et al.

Summary: Gold carbenes are highly active in homogeneous gold catalysis, facilitating various transformations including C-H/X-H insertions, cyclopropanations, and 1,2-migrations. While 1,2-migrations onto gold carbene centers have received less attention compared to other reactions, they have the potential to be a powerful tool for constructing molecular complexity rapidly and simply.

CHEMICAL REVIEWS (2021)

Article Chemistry, Organic

Molybdenum-Catalyzed Deoxygenative Cyclization of Carbonyl Compounds for the Synthesis of Pyrido[2,1-a]isoindoles

Sobi Asako et al.

Summary: A simple catalytic system composed of Mo(0) and ortho-quinone as catalyst, and phosphine as a reductant, has been developed for the synthesis of pyridoisoindoles and pyridoisoindolium salts through deoxygenation of carbonyl compounds.

ASIAN JOURNAL OF ORGANIC CHEMISTRY (2021)

Article Chemistry, Multidisciplinary

α-Imino Gold Carbene Intermediates from Readily Accessible Sulfilimines: Intermolecular Access to Structural Diversity

Xianhai Tian et al.

CHEMISTRY-A EUROPEAN JOURNAL (2020)

Article Chemistry, Multidisciplinary

Transition-Metal-Catalyzed Cross-Coupling with Ketones or Aldehydes via N-Tosylhydrazones

Ying Xia et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

Article Chemistry, Multidisciplinary

Grubbs Metathesis Enabled by a Light-Drivengem-Hydrogenation of Internal Alkynes

Tobias Biberger et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Article Chemistry, Multidisciplinary

Non-Diazo C-H Insertion Approach to Cyclobutanones through Oxidative Gold Catalysis

Zhitong Zheng et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Article Chemistry, Multidisciplinary

Hydrogenative Metathesis of Enynes via Piano-Stool Ruthenium Carbene Complexes Formed by Alkyne gem-Hydrogenation

Sebastian Peil et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

Article Chemistry, Multidisciplinary

Total Synthesis of (-)-Mitrephorone A Enabled by Stereoselective Nitrile Oxide Cycloaddition and Tetrasubstituted Olefin Synthesis

Michael Schneider et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

Review Chemistry, Multidisciplinary

Recent progress on donor and donor-donor carbenes

Dong Zhu et al.

CHEMICAL SOCIETY REVIEWS (2020)

Article Chemistry, Multidisciplinary

Deoxygenative Insertion of Carbonyl Carbon into a C(sp3)-H Bond: Synthesis of Indolines and Indoles

Sobi Asako et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

Article Multidisciplinary Sciences

Design and application of α-ketothioesters as 1,2-dicarbonyl-forming reagents

Ming Wang et al.

NATURE COMMUNICATIONS (2019)

Article Chemistry, Multidisciplinary

Sulfilimines as Versatile Nitrene Transfer Reagents: Facile Access to Diverse Aza-Heterocycles

Xianhai Tian et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Review Chemistry, Multidisciplinary

trans-Hydrogenation, gem-Hydrogenation, and trans-Hydrometalation of Alkynes: An Interim Report on an Unorthodox Reactivity Paradigm

Alois Fuerstner

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

Review Chemistry, Organic

Oxidation of amine α-carbon to amide: a review on direct methods to access the amide functionality

P. Nagaraaj et al.

ORGANIC CHEMISTRY FRONTIERS (2019)

Article Chemistry, Multidisciplinary

Palladium-Catalyzed Oxygenative Cross-Coupling of Ynamides and Benzyl Bromides by Carbene Migratory Insertion

Yunpeng Gao et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

Article Chemistry, Multidisciplinary

Highly Chemo- and Stereoselective Catalyst-Controlled Allylic C-H Insertion and Cyclopropanation Using Donor/Donor Carbenes

Dong Zhu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

Review Chemistry, Organic

Recent advances in the synthesis of cyclopropanes

Wanqing Wu et al.

ORGANIC & BIOMOLECULAR CHEMISTRY (2018)

Article Chemistry, Organic

Dichlorodioxomolybdenum(VI) Complexes: Useful and Readily Available Catalysts in Organic Synthesis

Raquel Hernandez-Ruiz et al.

SYNTHESIS-STUTTGART (2018)

Article Chemistry, Multidisciplinary

Use of Cyclopropane as C1 Synthetic Unit by Directed Retro-Cyclopropanation with Ethylene Release

Sobi Asako et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

Article Chemistry, Multidisciplinary

Total Synthesis of (-)-Mitrephorone A

Matthieu J. R. Richter et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

Article Chemistry, Organic

Recent renewed interest in the classical Kukhtin-Ramirez adducts

Yiyi Liu et al.

TETRAHEDRON LETTERS (2018)

Review Chemistry, Multidisciplinary

Transition-Metal-Catalyzed Cross-Couplings through Carbene Migratory Insertion

Ying Xia et al.

CHEMICAL REVIEWS (2017)

Review Chemistry, Multidisciplinary

Cyclopropanation Strategies in Recent Total Syntheses

Christian Ebner et al.

CHEMICAL REVIEWS (2017)

Article Chemistry, Applied

Molybdenum-Catalyzed Stereospecific Deoxygenation of Epoxides to Alkenes

Sobi Asako et al.

ADVANCED SYNTHESIS & CATALYSIS (2016)

Review Chemistry, Multidisciplinary

New Approaches to the Synthesis of Metal Carbenes

Minqiang Jia et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)

Article Chemistry, Multidisciplinary

Stabilization of a Chiral Dirhodium Carbene by Encapsulation and a Discussion of the Stereochemical Implications

Christophe Werle et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)

Article Chemistry, Multidisciplinary

Enantioselective Intramolecular C-H Insertion of Donor and Donor/Donor Carbenes by a Nondiazo Approach

Dong Zhu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)

Review Chemistry, Multidisciplinary

Au-Catalysed oxidative cyclisation

Zhitong Zheng et al.

CHEMICAL SOCIETY REVIEWS (2016)

Article Chemistry, Multidisciplinary

Structures of Reactive Donor/Acceptor and Donor/Donor Rhodium Carbenes in the Solid State and Their Implications for Catalysis

Christophe Werle et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)

Review Chemistry, Multidisciplinary

Modern Organic Synthesis with α-Diazocarbonyl Compounds

Alan Ford et al.

CHEMICAL REVIEWS (2015)

Review Chemistry, Multidisciplinary

Gold-Catalyzed Rearrangements and Beyond

Carla Obradors et al.

ACCOUNTS OF CHEMICAL RESEARCH (2014)

Review Chemistry, Multidisciplinary

A Non-Diazo Approach to α-Oxo Gold Carbenes via Gold-Catalyzed Alkyne Oxidation

Liming Zhang

ACCOUNTS OF CHEMICAL RESEARCH (2014)

Review Chemistry, Multidisciplinary

Reactions of metallocarbenes derived from N-sulfonyl-1,2,3-triazoles

Huw M. L. Davies et al.

CHEMICAL SOCIETY REVIEWS (2014)

Article Chemistry, Multidisciplinary

Development of a Concise Synthesis of (+)-Ingenol

Steven J. McKerrall et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)

Article Chemistry, Multidisciplinary

Palladium-Catalyzed Oxidative Cycloaddition through C-H/N-H Activation: Access to Benzazepines

Lei Wang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2013)

Article Chemistry, Multidisciplinary

Stoichiometric C=O Bond Oxidative Addition of Benzophenone by a Discrete Radical Intermediate To Form a Cobalt(I) Carbene

Seth L. Marquard et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2013)

Article Multidisciplinary Sciences

Direct Spectroscopic Characterization of a Transitory Dirhodium Donor-Acceptor Carbene Complex

Katherine P. Kornecki et al.

SCIENCE (2013)

Review Chemistry, Multidisciplinary

Recent advances in the total synthesis of cyclopropane-containing natural products

David Y. -K. Chen et al.

CHEMICAL SOCIETY REVIEWS (2012)

Article Chemistry, Multidisciplinary

Three-Component Synthesis of Ynediones by a Glyoxylation/Stephens-Castro Coupling Sequence

Eugen Merkul et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2011)

Article Chemistry, Multidisciplinary

Catalytic Syntheses of N-Heterocyclic Ynones and Ynediones by In Situ Activation of Carboxylic Acids with Oxalyl Chloride

Christina Boersch et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2011)

Review Chemistry, Multidisciplinary

New Syntheses of Diazo Compounds

Gerhard Maas

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2009)

Review Chemistry, Organic

Applications of Dioxomolybdenum(VI) Complexes to Organic Synthesis

Roberto Sanz et al.

CURRENT ORGANIC SYNTHESIS (2009)

Article Chemistry, Applied

Dioxomolybdenum(VI)-catalyzed reductive cyclization of nitro-aromatics.: Synthesis of carbazoles and indoles

Roberto Sanz et al.

ADVANCED SYNTHESIS & CATALYSIS (2007)

Article Chemistry, Multidisciplinary

Diindolylquinoxalines: Effective indole-based receptors for phosphate anion

Jonathan L. Sessler et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2006)

Review Chemistry, Multidisciplinary

Ruthenium-catalysed carbenoid cyclopropanation reactions with diazo compounds

G Maas

CHEMICAL SOCIETY REVIEWS (2004)

Article Chemistry, Organic

N-allyl-1,3-oxazines via a facile keto-ene/cyclization tandem reaction

RG Brinson et al.

TETRAHEDRON LETTERS (2004)

Article Chemistry, Multidisciplinary

Total synthesis of the duocarmycins

K Yamada et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2003)

Review Chemistry, Multidisciplinary

Synthesis and properties of oligocyclopropyl-containing natural products and model compounds

J Pietruszka

CHEMICAL REVIEWS (2003)

Review Chemistry, Multidisciplinary

Stereoselective cyclopropanation reactions

H Lebel et al.

CHEMICAL REVIEWS (2003)

Article Chemistry, Multidisciplinary

The first total synthesis of (±)-ingenol

JD Winkler et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2002)

Review Chemistry, Multidisciplinary

Reactions of alpha-diketones and o-quinones with phosphorus compounds

FH Osman et al.

CHEMICAL REVIEWS (2002)

Review Chemistry, Organic

Synthesis of cyclopropane containing natural products

WA Donaldson

TETRAHEDRON (2001)

Article Chemistry, Inorganic & Nuclear

On the evolution of organozinc carbenoid chemistry from carbonyl compounds - a personal account

WB Motherwell

JOURNAL OF ORGANOMETALLIC CHEMISTRY (2001)