Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 60, Issue 29, Pages 15798-15802Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.202016699
Keywords
boron; cycloaddition; dibenzoperylene; nitrogen; polycycles
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Funding
- Vector Foundation
- state of Baden-Wurttemberg through bwHPC
- German Research Foundation (DFG) [INST 40/575-1 FUGG]
- Projekt DEAL
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A novel strategy for incorporating the oxadiazadiborinane ring into the scaffold of a polycyclic aromatic hydrocarbon via cycloaddition-dehydration has been developed, resulting in highly emissive compounds.
Cycloaddition-dehydration involving a BNBN-butadiene analogue at the bay region of a dibenzoperylene and a non-enolizable aldehyde provides a novel strategy for incorporation of the oxadiazadiborinane (B2N2CO) ring into the scaffold of a polycyclic aromatic hydrocarbon resulting in highly emissive compounds.
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