4.8 Article

Bioinspired Color Switchable Photonic Crystal Silicone Elastomer Kirigami

Journal

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 60, Issue 26, Pages 14307-14312

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.202103045

Keywords

bioinspired; color switchable; kirigami; silicone elastomers

Funding

  1. National Natural Science Foundation of China (NSFC) [22073107, 22075009, 51961130388, 21875010, 21522308, 51522301, 51573192, 51775299, 52075287, 21273017, 51103004]
  2. Newton Advanced Fellowship [NAF\R1\191235]
  3. Beijing Natural Science Foundation [JQ19006]
  4. 111 Project [B14009]

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Bioinspired dynamic structural color is demonstrated in a flexible, mechanically triggered color switchable sheet, showing excellent color stability even after recycling over 10,000 times. Finite element modeling reveals that the thickness of PDMS kirigami and the chamfer at the incision play crucial roles in the out-of-plane deformation through in-plane stretching. This bioinspired PhC-PDMS kirigami exhibits robust functionality, technical flexibility, and mechanical durability, making it suitable for a variety of applications.
Bioinspired dynamic structural color has great potential for use in dynamic displays, sensors, cryptography, and camouflage. However, it is quite rare for artificial structural color devices to withstand thousands of cycles. Male hummingbird's crowns and gorgets are brightly colored, demonstrating frequent color switching that is induced by regulating the orientation of the feathers through movement of skin or joints. Inspired by this unique structural color modulation, we demonstrate a flexible, mechanically triggered color switchable sheet based on a photonic crystal (PhC)-coated polydimethylsiloxane (PDMS) kirigami (PhC-PDMS kirigami) made by laser cutting. Finite element modeling (FEM) simulation reveals that the thickness of PDMS kirigami and the chamfer at the incision induced by laser cutting both dominate the out-of-plane deformation through in-plane stretching. The bioinspired PhC-PDMS kirigami shows precisely programmable structural color and keeps the color very well after recycling over 10 000 times. This bioinspired PhC-PDMS kirigami also shows excellent viewability even in bright sunlight, high readability, robust functionality, technical flexibility, and mechanical durability, which are readily exploitable for applications, such as chromic mechanical monitors for the sports industry or for medical applications, wearable camouflage, and security systems.

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