Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 363, Issue 13, Pages 3354-3358Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.202100316
Keywords
Aniline; C− H bond activation; Heterocycles; Hypervalent iodine; Intramolecular cyclization
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Funding
- Ministry of Education, Culture, Sports, Science and Technology of Japan [G19K05469]
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A new synthetic method was developed with the use of aniline-type hypervalent iodine(III) for direct cyclizations, resulting in high yields of the corresponding products.
We developed a method for the preparation of (diacetoxyiodo)-2-(N-alkylamido)benzene as an aniline-type hypervalent iodine(III). We also achieved direct cyclizations via C-H bond abstraction, such as the Hofmann-Loffler-Freytag reaction, a direct amination, and a direct lactonization, using the aniline-type hypervalent iodine(III) to obtain corresponding products in high yields.
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