Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 363, Issue 14, Pages 3471-3475Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.202100285
Keywords
Manganese complex; Hydrogenative cross-coupling; Nitrile; Amine; Secondary imine
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Funding
- National Natural Science Foundation of China [21790330, 21532003, 91956000]
- 111 project of the Ministry of Education of China [B06005]
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Manganese complexes with tridentate PNN ligands have been synthesized as catalysts for hydrogenative cross-coupling reaction of nitriles and amines to form secondary imines. This reaction yielded a variety of unsymmetrical secondary imines in good yields with excellent selectivity. Investigation of catalyst intermediates suggested that an amido manganese complex may be the active catalyst species for this reaction.
Manganese complexes with tridentate PNN ligands have been synthesized as catalysts for hydrogenative cross-coupling reaction of nitriles and amines to form secondary imines. This reaction afforded a variety of unsymmetrical secondary imines in good yields with excellent selectivity. Investigation of catalyst intermediates indicated that an amido manganese complex may be the active catalyst species for this reaction.
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