A 3D Plasmonic Antenna-Reactor for Nanoscale Thermal Hotspots and Gradients

Plasmonic nanoantennas focus light below the diffraction limit, creating strong field enhancements, typically within a nanoscale junction. Placing a nanostructure within the junction can greatly enhance the nanostructure's innate optical absorption, resulting in intense photothermal heating that could ultimately compromise both the nanostructure and the nanoantenna. Here, we demonstrate a three-dimensional antennareactor geometry that results in large nanoscale thermal gradients, inducing large local temperature increases in the confined nanostructure reactor while minimizing the temperature increase of the surrounding antenna. The nanostructure is supported on an insulating substrate within the antenna gap, while the antenna maintains direct contact with an underlying thermal conductor. Elevated local temperatures are quantified, and high local temperature gradients that thermally reshape only the internal reactor element within each antenna-reactor structure are observed. We also show that high local temperature increases of nominally 200 degrees C are achievable within antenna-reactors patterned into large extended arrays. This simple strategy can facilitate standoff optical generation of high-temperature hotspots, which may be useful in applications such as small-volume, high-throughput chemical processes, where reaction efficiencies depend exponentially on local temperature.

Automated summary

A three-dimensional antennareactor geometry is demonstrated to induce large nanoscale thermal gradients, resulting in significant local temperature increases in the confined nanostructure reactor while minimizing temperature increase of the surrounding antenna. This strategy allows for high local temperature increases of nominally 200 degrees C achievable within antenna-reactors patterned into large extended arrays, which could have applications in small-volume, high-throughput chemical processes.