4.8 Article

Rare Earth Orthoferrite Tuning of Transmitted Waves as Natural Metamaterials

Journal

ACS APPLIED MATERIALS & INTERFACES
Volume 13, Issue 20, Pages 23884-23893

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsami.1c02588

Keywords

functional inorganic materials and devices; natural metamaterials; optical transmission; ceramics; rare earth orthoferrites

Funding

  1. National Key Research and Development Program of China [2017YFB0406300]
  2. National Natural Science Foundation of China [51788104, 51532004]
  3. Postdoctoral Innovative Talent Support Program [BX20190032]
  4. China Postdoctoral Science Foundation [2019M660450]
  5. Fundamental Research Funds for the Central Universities [FRF06500142]
  6. Science and Technology Plan of Shenzhen City [JCYJ20170817162221169, JCYJ20170817162252290, JCYJ20180507182429941]

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Research on using rare earth orthoferrites to tune transmitted waves by engineering thickness, composition, and temperature showed that thickness engineering conformed to the Beer-Lambert law, while doping had a strong impact on the transmitted waves. Additionally, a thermal anisotropic energy manipulation approach was developed by lowering the temperature. Rare earth orthoferrites are effective media in the THz range and show characteristics of natural metamaterials.
Metamaterials display many electromagnetic properties, such as the manipulation of electromagnetic waves through the arrangement of small discrete structures. However, complex designs of mechanically or electrically patterned structures are required to modify these properties. We report on the use of rare earth orthoferrites to tune transmitted waves by engineering the thickness, composition, and temperature using terahertz (THz) time-domain spectroscopy. The modeling of the process of manipulating the transmitted waves helps to elucidate the manipulated amplitude, transmittance, peak height, and frequency. The effectiveness of thickness engineering in tuning the transmitted waves, which conformed to the Beer-Lambert law, was demonstrated. The transmitted waves were also strongly affected by doping. In addition, a thermal anisotropic energy manipulation approach to tuning transmitted waves was developed by lowering the temperature. Rare earth orthoferrites are a kind of effective medium in the THz range and exhibit the signature of natural metamaterials.

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