Journal
ACS APPLIED MATERIALS & INTERFACES
Volume 13, Issue 18, Pages 21390-21400Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsami.1c03642
Keywords
Na3MnZr(PO4)(3); dual carbon; temperature adaptability; electrochemical performance; sodium-ion batteries
Funding
- National Natural Science Foundation of China [21603040]
- Natural Science Foundation of Guangxi [2017GXNSFAA198338]
- Key Research and Development Program of Guangxi [AB19110024]
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A scalable spray-drying strategy was proposed to construct interconnected conductive networks in microspheres, which showed excellent rate performance and long-term cycling stability in a wide temperature range for sodium-ion batteries.
Polyanionic cathode materials that have high energy density and good temperature adaptability are in high demand for practical applications in sodium-ion batteries (SIBs). In this study, a scalable spray-drying strategy has been proposed to construct interconnected conductive networks composed of amorphous carbon and reduced graphene oxide in Na3MnZr(PO4)(3) microspheres (NMZP@C-rGO). The dual-carbon conductive networks provide fast electron migration pathways in the microspheres. Moreover, they significantly increase the porosity and specific surface area of the microspheres, which are conducive to accommodating the volume change and improving the electrode/electrolyte contact interface and the contribution of the pseudocapacitance effect to achieve fast sodium storage. As a result, NMZP@C-rGO exhibits excellent rate performance (50.9 mAh g(-1) at 50C and 30 degrees C, 35.4 mAh g(-1) at 50C and -15 degrees C) and long-term cycling stability (capacity retentions of 97.4 and 79.6% after 1500 cycles at 30 and -15 degrees C, respectively) in a wide temperature range.
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