4.8 Article

Enhancing the Performance of Fabric-Based Triboelectric Nanogenerators by Structural and Chemical Modification

Journal

ACS APPLIED MATERIALS & INTERFACES
Volume 13, Issue 14, Pages 16916-16927

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsami.1c02815

Keywords

triboelectric nanogenerator; fabric; surface modification; energy harvesting; wearable device

Funding

  1. Natural Science Foundation of Hunan Province [2020JJ4266]
  2. Research Project of the Educational Commission of Hunan Province [18B297]
  3. Research Grants Council of Hong Kong [PolyU 152099/18E, PolyU 15204719/18E]

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A chemical method was proposed to enhance the triboelectric performance of commercial velvet fabric, achieving significant improvement in output voltage and current at low modifier content, making it suitable for powering various small electronics with good washability and stability.
Fabric-based triboelectric nanogenerators (TENGs) are promising candidates as wearable energy-harvesting devices and self-powered sensors. Booting the power generation performance is an eternal pursuit for TENGs. Herein, an efficient approach was proposed to enhance the triboelectric performance of commercial velvet fabric by enriching the fiber surface with hierarchical structures and amide bonds through chemical grafting of carbon nanotube (CNT) and poly(ethylenimine) (PEI) via a polyamidation reaction. With an optimized modifier concentration, the fabric-based TENG easily achieved over 10 times improvement in output voltage and current at a low modifier content of less than 1 wt %. The modified-fabric-based TENG was fully washable and exhibited excellent robustness and long-term stability. With a maximum power density of 3.2 W/m(2) achieved on a 5 x 10(6) Omega external resistor, the TENG was able to serve as a power source for various small electronics such as pedometer, digital watch, calculator, and digital timer. In addition, the TENG demonstrated capability in self-powered tactile and pressure sensing and promising potential in human-computer interface applications. The approach proposed provides a feasible path for boosting the triboelectric performance of fabric-based TENGs and gives insights into the design of fabric-based nanogenerators and smart textiles.

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