4.8 Article

Alternating Multilayered Si3N4/SiC Aerogels for Broadband and High-Temperature Electromagnetic Wave Absorption up to 1000 °C

Journal

ACS APPLIED MATERIALS & INTERFACES
Volume 13, Issue 14, Pages 16704-16712

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsami.1c02906

Keywords

SiC; aerogel; alternating multilayered structure; electromagnetic wave absorption; thermal insulation

Funding

  1. National Natural Science Foundation of China [52072294, 51772237]
  2. Characteristic Development Guidance Funds for the Central Universities

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Inspired by the energy dissipation mechanism of lobster shells, researchers have developed a high-performance ceramic aerogel with alternating multilayered structure for excellent electromagnetic wave absorption performance at high temperatures.
Lightweight electromagnetic (EM) wave absorbers made of ceramics have sparked tremendous interest for applications in EM wave interference protection at high temperatures. However, EM wave absorption by pure ceramics still faces huge challenges due to the lack of efficient EM wave attenuation modes. Inspired by the energy dissipation mechanism during fracture of lobster shells with a soft and stiff multilayered structure, we fabricate a high-performance EM wave absorption ceramic aerogel composed of an alternating multilayered wave transparent Si3N4 (N) layer and wave absorption SiC (C) layer by a simple restack method. The obtained N/C aerogel shows ultralow density (similar to 8 mg/cm(3)), broad effective absorption bandwidth (8.4 GHz), strong reflection loss (-45 dB) at room temperature, and excellent EM wave absorption performance at high temperatures up to 1000 degrees C. The attenuation of EM wave mainly results from a reflection-absorption-zigzag reflection process caused by the alternating multilayered structure. The superior absorption performance, especially at high temperatures, makes the N/C aerogel promising for next-generation wave absorption devices served in high-temperature environments.

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