Journal
ACS APPLIED MATERIALS & INTERFACES
Volume 13, Issue 20, Pages 23558-23566Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsami.1c01621
Keywords
metal-organic frameworks; polyoxometalate; double-solvent; ship in a bottle catalyst; one-pot reaction; Knoevenagel reaction; bifunctional catalyst
Funding
- Ghent University [01SC0619]
- China Scholarship Council (CSC)
- Ghent University BOF doctoral grant [01D04318]
- International S&T Cooperation Program of China [2016YFE0109800]
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The study presents an effective bifunctional heterogeneous catalyst by encapsulating a polyoxometalate into the cages of an alkylamine-modified MIL-101, achieving a great catalytic performance for the selective oxidation-Knoevenagel one-pot reaction with 99% conversion rate.
One-pot reactions offer economic and environmental advantages. Therefore, the design and synthesis of multifunctional catalysts capable of catalyzing multistep organic transformations are highly important. Herein, an effective bifunctional heterogeneous catalyst is presented. For the first time, the encapsulation of H5PMo10V2O40 (PMoV2) polyoxometalate into the cages of an alkylamine-modified MIL-101 using an optimized double-solvent method is reported. The obtained PMoV2@DETA-MIL-101 material displays a great catalytic performance (99% conversion of alcohols) for the selective aerobic oxidation-Knoevenagel one-pot reaction. To the best of our knowledge, this is one of the first reports on the usage of noble-metal-free catalysts for the aerobic oxidation-Knoevenagel one-pot reaction without the addition of additives. The catalyst is very stable and can be used for at least five cycles with no leaching of the active sites.
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