4.5 Review

Metal-Oxide Nanowire Molecular Sensors and Their Promises

Journal

CHEMOSENSORS
Volume 9, Issue 2, Pages -

Publisher

MDPI
DOI: 10.3390/chemosensors9020041

Keywords

nanowire; oxide; gas sensor; device; 1D nanostructure; sensing mechanism

Funding

  1. KAKENHI [JP17H04927, JP18H01831, JP18H05243, JP18KK0112]
  2. JST PRESTO, Japan [JPMJPR19T8, JPMJPR19J7, JPMJPR19M6]
  3. JST CREST, Japan [JPMJCR19I2]
  4. CAS-JSPS Joint Research Projects [JPJSBP120187207]
  5. Mirai RD of JST

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This review provides a comprehensive overview of the recent studies and achievements in 1D metal-oxide nanowire-based molecular sensors, discussing their potential in sensor electronics and highlighting key issues that impede their practical application. The review also offers a prospective account of the remaining challenges towards the laboratory-to-market transformation of sensor electronics based on 1D nanostructures.
During the past two decades, one-dimensional (1D) metal-oxide nanowire (NW)-based molecular sensors have been witnessed as promising candidates to electrically detect volatile organic compounds (VOCs) due to their high surface to volume ratio, single crystallinity, and well-defined crystal orientations. Furthermore, these unique physical/chemical features allow the integrated sensor electronics to work with a long-term stability, ultra-low power consumption, and miniature device size, which promote the fast development of trillion sensor electronics for Internet of things (IoT) applications. This review gives a comprehensive overview of the recent studies and achievements in 1D metal-oxide nanowire synthesis, sensor device fabrication, sensing material functionalization, and sensing mechanisms. In addition, some critical issues that impede the practical application of the 1D metal-oxide nanowire-based sensor electronics, including selectivity, long-term stability, and low power consumption, will be highlighted. Finally, we give a prospective account of the remaining issues toward the laboratory-to-market transformation of the 1D nanostructure-based sensor electronics.

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