Operando Particle-Scale Characterization of Silicon Anode Degradation during Cycling by Ultrahigh-Resolution X-ray Microscopy and Computed Tomography

A combination of two-dimensional (2D) operando transmission X-ray radiograph sequences and three-dimensional (3D) in situ X-ray computed tomography was used to characterize a composite silicon anode during cycling in an electrode and coin cell format consistent with commercial lithium-ion (Li-ion) batteries. Silicon (Si) particle expansion and phase transformation within the porous electrode were imaged continuously during cycling at various rates at O(100 nm) resolution within a large O(100 mu m) region of interest that capture electrode-scale effects. The imaging utilizes the substantial change in the 8 keV X-ray absorption coefficient with lithium (Li) alloying of Si during charging. At low rate cycling, the X-ray signal attenuation over the Si particles decreased with increased lithiation. In contrast, at high rate cycling, we observe increased attenuation at the electrode scale. A useful feature of this operando imaging is the simultaneous imaging of a large number of particles in close proximity. To capture the transformations of such a large number of Si during cycling, we introduce a standard deviation analysis of the operando transmission X-ray radiograph sequences. At key instances in the cycling, the same region of interest from the radiographs was reconstructed into 3D volumes. Si particle fracture, electrode expansion, and particle detachment from the current collector were all observed in the reconstructed volumes. This study demonstrates the unique capability of the combined 2D operando and 3D in situ X-ray imaging techniques in investigating the dynamic behavior of battery materials at the sub-micrometer particle scale in commercially relevant electrode formats.

Automated summary

By combining 2D operando transmission X-ray radiograph sequences with 3D in situ X-ray computed tomography, this study characterized the behavior of a composite silicon anode during cycling in lithium-ion batteries. The X-ray signal attenuation over Si particles decreased with increased lithiation at low cycling rates, whereas increased attenuation was observed at electrode scale during high cycling rates. The simultaneous imaging of a large number of particles in close proximity was a useful feature of this operando imaging technique.