Journal
JOURNAL OF MATERIOMICS
Volume 7, Issue 5, Pages 967-975Publisher
ELSEVIER
DOI: 10.1016/j.jmat.2021.03.006
Keywords
Bi1-xGdxFeO3; Morphotropic phase boundary; Magnetic properties; Electric-field-controlled magnetism
Funding
- National Key R&D Program of China [2016YFA0300101]
- National Natural Science Foundation of China [51790493, 51961145105]
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Electric-field-controlled magnetism is achieved in the Bi1-xGdxFeO3 system, involving a field-induced transition of Pna21/R3c and reversible magnetism with annealing. This leads to more significant electric-field-controlled magnetism compared to other systems in a wider composition range.
BiFeO3 has been recognized as one of the most important room-temperature single-phase multiferroic materials, but it still suffers from several drawbacks especially the weak magnetoelectric coupling. In the present work, the electric-field-controlled magnetism is achieved in Bi1-xGdxFeO3 system, which involves a field-induced transition of Pna21/R3c at the morphotropic phase boundary region, and the magnetic state is switched between cycloidal state and canted antiferromagnetic state. The electric-field-controlled magnetism becomes reversible with the help of annealing, which is confirmed by magnetic hysteresis loops and the quantitative ratio of the involved phases for the as-sintered, as-poled and as-annealed samples. Compared with the systems of Bi1-xNdxFeO3 and Bi1-xSmxFeO3, it is easier to tune the symmetry from R3c to Pna21 with lower rare earth-content, and the field-induced transition is more apparent and subsequently leads to more significant electric-field-controlled magnetism in a wider composition range. (C) 2021 The Chinese Ceramic Society. Production and hosting by Elsevier B.V.
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