4.7 Article

Electron-phonon coupling in superconducting 1T-PdTe2

Journal

NPJ 2D MATERIALS AND APPLICATIONS
Volume 5, Issue 1, Pages -

Publisher

NATURE RESEARCH
DOI: 10.1038/s41699-021-00204-5

Keywords

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Funding

  1. Ministerio de Economia y Competitividad (MINECO) [MAT2015-65356-C3-3-R, FIS2015-67367 C2-1-P]
  2. Ministerio de Ciencia, Innovacion y Universidades [PGC2018-093291-B-I00, PGC2018-097028-A-I00, PGC2018-098613-B-C21, PID2019-109525RB-I00]
  3. Comunidad de Madrid (CM) projects Nanomag COST-CM [P2018/NMAT-4321, NMAT2D-CM P2018/NMT-4511]
  4. Spanish Ministry of Science and Innovation [PID2019-109525RB-I00]
  5. Maria de Maeztu Programme for Units of Excellence in RD [CEX2018-000805-M]
  6. 'Severo Ochoa' Programme for Centres of Excellence in RD (MINECO) [SEV-2016-0686]
  7. Postdoctoral Junior Leader Fellowship Programme from la Caixa Banking Foundation

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The electron-phonon interaction in type II Dirac semimetallic 1T-PdTe2 has been determined using helium atom scattering, indicating a substantial electron-phonon coupling which is crucial for its superconductivity. This coupling value, along with the surface Debye temperature, accurately predicts the superconducting critical temperature, suggesting that the topological states of a Dirac cone have minimal influence on the onset of superconductivity.
We have determined the electron-phonon interaction in type II Dirac semimetallic 1T-PdTe2 by means of helium atom scattering. While 1T-PdTe2 is isostructural with 1T-PtTe2, only the former is superconductor. The difference can be traced to the substantially larger value of the electron-phonon coupling in 1T-PdTe2, lambda = 0.58, obtained from the Debye-Waller attenuation of the He specular peak. With this value and the surface Debye temperature, Theta(D) = 106.2 K, we have figured out the superconducting critical temperature, T-c = 1.83 K given by the BCS theory, which is in good agreement with T-c = (1.95 +/- 0.03) K obtained with low-temperature scanning tunneling microscopy. The value of the effective mass related to Theta(D) indicates that the large electron-phonon coupling in 1T-PdTe2 is due to coupling, not only with the zone-center optical mode O-2 at 9.2 meV, as proposed in a recent theoretical study, but also with the zone-boundary acoustic mode LA. Our results suggest that the topological states of a Dirac cone play a negligible role on the onset of superconductivity.

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