4.6 Article

Imidazoline Gemini Surfactants as Corrosion Inhibitors for Carbon Steel X70 in NaCl Solution

Journal

ACS OMEGA
Volume 6, Issue 8, Pages 5653-5660

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsomega.0c06103

Keywords

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Funding

  1. National Natural Science Foundation of China [21703194]
  2. Fundamental Research Funds for the Central Universities [20CX05015A]
  3. Special Fund for Promoting Scientific and Technological Innovation of Xuzhou [KC17080]

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Gemini imidazoline surfactants derived from saturated fatty acids show excellent inhibition effect on X70 carbon steel in NaCl solution. The suppression efficiency is better in alkaline solution than in neutral solution, with shorter carbon chain length corresponding to higher efficiency. Additionally, higher concentration of the surfactant leads to better inhibition effect.
The Gemini imidazoline surfactants were synthesized from a series of saturated fatty acids. Electrochemical impedance spectroscopy (EIS), polarization curve, and quantum chemistry methods were used to study the corrosion inhibition behavior of Gemini imidazoline surfactants for X70 carbon steel in NaCl solution. Results reveal that such kind of surfactants has an outstanding inhibition effect on carbon steel X70 in NaCl solution and that the restrained efficiency of Gemini imidazoline in an alkaline solution is better than that in a neutral solution. The shorter the carbon chain length, the higher the suppressive efficiency. The higher the concentration of Gemini imidazoline surfactant, the better the inhibition effect.

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