Journal
PROCESSES
Volume 9, Issue 2, Pages -Publisher
MDPI
DOI: 10.3390/pr9020375
Keywords
polymer grafting; polymer synthesis; polymer characterization; mathematical modeling; polymer reaction engineering; reversible deactivation radical polymerization
Categories
Funding
- Consejo Nacional de Ciencia y Tecnologia (CONACYT, Mexico)
- DGAPA-UNAM [PAPIIT IG100718, IV100119, TA100818, TA102120]
- Facultad de Quimica, UNAM [PAIP 5000-9078, PAIP 5000-9167]
- NSERC
- Department of Chemical Engineering, University of Waterloo, Canada
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This critical review focuses on the synthesis, characterization, and modeling of polymer grafting, pointing out that there is room for further research in this area despite existing understanding and efforts.
A critical review on the synthesis, characterization, and modeling of polymer grafting is presented. Although the motivation stemmed from grafting synthetic polymers onto lignocellulosic biopolymers, a comprehensive overview is also provided on the chemical grafting, characterization, and processing of grafted materials of different types, including synthetic backbones. Although polymer grafting has been studied for many decades-and so has the modeling of polymer branching and crosslinking for that matter, thereby reaching a good level of understanding in order to describe existing branching/crosslinking systems-polymer grafting has remained behind in modeling efforts. Areas of opportunity for further study are suggested within this review.
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