Journal
SCIENCE CHINA-MATERIALS
Volume 64, Issue 8, Pages 1889-1899Publisher
SCIENCE PRESS
DOI: 10.1007/s40843-020-1590-x
Keywords
oxygen evolution reaction; cobalt nitrides; heteroatom doping; electronic state; nanowire bundles
Categories
Funding
- China Postdoctoral Science Foundation [2020M673056]
- National Key Research and Development Program of China [2018YFA0209402]
- National Natural Science Foundation of China [21773093]
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In this study, nickel doping was introduced into one-dimensional hierarchical Co4N structures to enhance OER performance, resulting in increased amount of Co3+ and improved electrocatalytic kinetics. The optimal Ni-doped Co4N with Ni/Co molar ratio of 0.25 exhibited excellent OER performance, with low overpotential and Tafel slope, as well as high long-term stability. Doping with Fe and Cu further enhanced the OER activity of Co4N nanowire bundles.
Cost-efficient electrocatalysts composed of earth-abundant elements are highly desired for enhanced oxygen evolution reaction (OER). As a promising candidate, metallic Co4N already demonstrated electrocatalytic performance relying on specific nanostructures and electronic configurations. Herein, nickel was introduced as the dopant into one-dimensional (1D) hierarchical Co4N structures, achieving effective electronic regulation of Co4N toward high OER performance. The amount of Co3+ increased after Ni-doping, and the in-situ formed surface oxyhydroxide during OER enhanced the electrocatalytic kinetics. Meanwhile, the 1D hierarchical structure further promoted the performances of Co4N owing to the high electrical conductivity and abundant active-sites on the rough surface. As expected, the optimal Ni-doped Co4N with a Ni/Co molar ratio of 0.25 provides a small overpotential of 233 mV at a current density of 10 mAcm(-2), with a low Tafel slope of 61 mV dec(-1), and high long-term stability in 1.0 mol L-1 KOH. Following these results, the enhancement by doping the Co4N nanowire bundles with Fe and Cu was further evidenced for the OER.
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