4.6 Article

Functionalized Carbon Nanotube and MnO2 Nanoflower Hybrid as an Electrode Material for Supercapacitor Application

Journal

MICROMACHINES
Volume 12, Issue 2, Pages -

Publisher

MDPI
DOI: 10.3390/mi12020213

Keywords

FCNT-MnO2; hydrothermal; supercapacitor; specific energy; specific power

Funding

  1. Centre for Carbon Materials of International Advanced Research Centre for Powder Metallurgy and New Materials (ARCI), Hyderabad, P.O. Balapur, Telangana, India
  2. Centre for Materials Characterization of International Advanced Research Centre for Powder Metallurgy and New Materials (ARCI), Hyderabad, P.O. Balapur, Telangana, India

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The study successfully synthesized a hybrid material of functionalized carbon nanotube and manganese oxide nanoflower for supercapacitor applications, showing promising electrochemical performance with high specific energy, specific power, and long cycle life potential.
Functionalized carbon nanotube (FCNT) and Manganese Oxide (MnO2) nanoflower hybrid material was synthesized using hydrothermal technique as a promising electrode material for supercapacitor applications. The morphological investigation revealed the formation of 'nanoflower' like structure of MnO2 connected with FCNT, thus paving an easy path for the conduction of electrons during the electrochemical mechanism. A significant improvement in capacitance properties was observed in the hybrid material, in which carbon nanotube acts as a conducting cylindrical path, while the major role of MnO2 was to store the charge, acting as an electrolyte reservoir leading to an overall improved electrochemical performance. The full cell electrochemical analysis of FCNT-MnO2 hybrid using 3 M potassium hydroxide (KOH) electrolyte indicated a specific capacitance of 359.53 F g(-1), specific energy of 49.93 Wh kg(-1) and maximum specific power of 898.84 W kg(-1) at 5 mV s(-1). The results show promise for the future of supercapacitor development based on hybrid electrode materials, where high specific energy can be achieved along with high specific power and long cycle life.

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