4.4 Article

Single Particle Inductively Coupled Plasma Mass Spectrometry Study of Ceria Nanoparticle Size Distribution from Oxide CMP with Microreplicated Pads

Journal

Publisher

ELECTROCHEMICAL SOC INC
DOI: 10.1149/2162-8777/abed9e

Keywords

Chemical mechanical planarization; Nanoscale materials; Silicon; Semiconductors; Microelectronics; Semiconductor Processing

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This study utilized spICP-MS to measure ceria particle number concentrations and compare changes in size distributions to silicon dioxide wafer removal rates during different CMP processes. The research found that changes in ceria particle size distribution were correlated with removal rates.
This work describes the use of Single Particle Inductively Coupled Plasma Mass Spectrometry (spICP-MS) to measure ceria particle number concentrations and compare changes in size distributions to silicon dioxide wafer removal rates from different chemical mechanical planarization (CMP) processes. Particle number concentrations were measured for the 21 to 559 nm size range at 1 nm size resolution. Changes in the ceria particle size distribution after CMP included a decrease in large (>130 nm) particles, an increase in small (<40 nm) particles, an increase in the total number of particles, and a decrease in median particle size. The decrease in median size was as high as 7% and influenced by flow rate, pressure and pad type. A novel microreplicated CMP pad was used which requires no pad conditioning to ensure consistent pad surface features, and the effect of different pad types on removal rate and particle size was isolated. A decrease in the median particle size correlated with higher silicon dioxide removal rates (R-2 = 0.96) for a series of pad types with unique combinations of chemistry and surface features. This new combination of nano particle metrology and control of pad surface features is an innovative tool set for modeling advanced CMP processes.

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