Journal
ACS SUSTAINABLE CHEMISTRY & ENGINEERING
Volume 9, Issue 8, Pages 3011-3042Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acssuschemeng.0c09229
Keywords
Biomass; F2B process; Bioderived chemicals; Furan derivatives; Benzene; Aromatic compounds; Sustainable development; Carbon-neutral industry
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The article discusses the current progress in converting cellulose biomass into valuable furanic platform chemicals, highlighting the key challenge of producing aromatic compounds and analyzing the development and future challenges of the F2B process.
Rapid development in the area of cellulose biomass conversion to furanic platform chemicals has led to expectations of their valuable practical use. Impressive research progress in this direction has resulted in several achievements but at the same time identified a key challenge-the necessity to produce aromatic compounds. In this perspective, we analyze the current stage of development of the furanics-to-benzene conversion process (F2B process) in connection with a bioderived route to aromatic compounds. Cycloaddition reactions between bioderived C6-furans as diene components and alkene/alkyne units are discussed in detail, followed by considering the subsequent aromatization reaction. Progress in the development of the F2B process and future challenges are outlined in this perspective. The key role of the F2B process in the overall biomass to aromatics transformation is discussed in view of the implementation of carbon neutral sustainable technologies in practice.
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