4.7 Article

Facile Post Treatment of Ag Nanowire/Polymer Composites for Flexible Transparent Electrodes and Thin Film Heaters

Journal

POLYMERS
Volume 13, Issue 4, Pages -

Publisher

MDPI
DOI: 10.3390/polym13040586

Keywords

silver nanowires; transparent conductive electrode; film heaters

Funding

  1. Korea Electric Power Corporation [R20XO02-13]
  2. Korea Institute of Industrial Technology (KITECH) [278, EO210001]
  3. Ministry of Trade, Industry & Energy (MOTIE), Republic of Korea [278] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
  4. National Research Council of Science & Technology (NST), Republic of Korea [EO210001] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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The typical polyol-based synthesis of silver nanowires using insulating polymer as a surfactant limits direct contact between each nanowire, affecting optoelectronic properties. A simple solvent treatment effectively removes the insulating polymer, leading to decreased sheet resistance and increased transmittance. Transparent film heaters using the treated silver nanowire network rapidly reached 150 degrees C under a bias of 5 V, demonstrating great potential for flexible transparent electrode and film heater applications.
Typical polyol-based synthesis of silver nanowire employs insulating polymer as a surfactant for the silver nanowire growth, which limits direct contact between each nanowire and thus its optoelectronic properties. We herein demonstrate that a simple solvent treatment effectively removes the insulating polymer around Ag NWs, leading to significantly decreased sheet resistance (similar to 12 Omega/sq) with an increased transmittance (81% @ T-550), as compared to other post-treatments. We successfully demonstrate the transparent film heaters using the solvent-treated Ag NWs network, which rapidly exhibited 150 degrees C under a bias of 5 V. Flexible film heaters on plastic substrate is also demonstrated, suggesting a great potential of the solvent treatment process of Ag NWs for flexible transparent electrode and film heater applications.

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