4.6 Article

Green large-scale production of N/O-dual doping hard carbon derived from bagasse as high-performance anodes for sodium-ion batteries

Journal

JOURNAL OF CENTRAL SOUTH UNIVERSITY
Volume 28, Issue 2, Pages 361-369

Publisher

JOURNAL OF CENTRAL SOUTH UNIV
DOI: 10.1007/s11771-021-4608-y

Keywords

anode; hard carbon; sodium-ion batteries; cycling stability; full cell

Funding

  1. National Natural Science Foundation of China [51661009, 51761007]
  2. Natural Science Foundation of Guangxi Province, China [2019GXNSFDA245014, 2016GXNSFGA380001]
  3. Science and Technology Base and Talent Special Project of Guangxi Province, China [2019AC20164, 2019AC20053]

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This study demonstrates that hard carbon derived from renewable bagasse is a promising anode material for sodium-ion batteries, with excellent electrochemical properties including high reversible capacity and good cycle stability. The simple and cost-effective preparation process adds to its potential for practical application in energy storage devices.
Sodium-ion batteries are considered as a promising candidate for lithium-ion batteries due to abundant sodium resources and similar intercalation chemistry. Hard carbon derived from biomass with the virtue of abundance and renewability is a cost-effective anode material. Herein, hard carbon is derived from renewable bagasse through a simple two-step method combining mechanical ball milling with carbonization. The hard carbon electrodes exhibit superior electrochemical performance with a high reversible capacity of 315 mA-h/g. Furthermore, the initial capacity of the full cell, HC//NaMn0.4Ni0.4Ti0.1Mg0.1O2, is 253 mA center dot h/g and its capacity retention rate is 77% after 80 cycles, which further verifies its practical application. The simple and low-cost preparation process, as well as excellent electrochemical properties, demonstrates that hard carbon derived from bagasse is a promising anode for sodium-ion batteries.

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