F/OH ratio in a rare fluorine-poor blue topaz from Padre Paraiso (Minas Gerais, Brazil) to unravel topaz's ambient of formation

Topaz [Al2SiO4(F,OH)(2)] is one of the main fluorine-bearing silicates occurring in environments where variably acidic (F)/aqueous (OH) fluids saturate the silicate system. In this work we fully characterized blue topaz from Padre Paraiso (Minas Gerais, Brazil) by means of in situ synchrotron X-Ray and neutron powder diffraction measurements (temperature range 298-1273 K) combined with EDS microanalyses. Understanding the role of OH/F substitution in topaz is important in order to determine the hydrophilicity and the exchange reactions of fluorine by hydroxyl groups, and ultimately to characterize the environmental redox conditions (H2O/F) required for mineral formation. The fluorine content estimated from neutron diffraction data is similar to 1.03 a.f.u (10.34 wt%), in agreement with the chemical data (on average 10.0 wt%). The X-OH [OH/(OH+F)] (0.484) is close to the maximum X-OH value (0.5), and represents the OH- richest topaz composition so far analysed in the Minas Gerais district. Topaz crystallinity and fluorine content sharply decrease at 1170 K, while mullite phase starts growing. On the basis of this behaviour, we suggest that this temperature may represent the potential initial topaz's crystallization temperature from supercritical fluids in a pegmatite system. The log(fH(2)O/fHF()fluid) (1.27 (0.06)) is coherent with the fluorine activity calculated for hydrothermal fluids (pegmatitic stage) in equilibrium with the forming mineral (log(fH(2)O/fHF)(fluid)=1.2-6.5) and clearly different from pure magmatic (granitic) residual melts [log(fH(2)O/fHF)(fluid)<1]. The modelled H2O saturated fluids with the F content not exceeding 1 wt% may represent an anomalous water-dominant / fluorine-poor pegmatite lens of the Padre Paraiso Pegmatite Field.

Automated summary

In this study, blue topaz from Padre Paraiso, Brazil was fully characterized through in situ synchrotron X-Ray and neutron powder diffraction measurements. The research focused on understanding the role of OH/F substitution in topaz and determining the hydrophilicity and exchange reactions of fluorine by hydroxyl groups during mineral formation. The findings suggest that 1170 K may represent the potential initial crystallization temperature of topaz from supercritical fluids in a pegmatite system.